A full voltage sampling circuit includes a main sampling circuit, an assist sampling circuit and a processing circuit. The main sampling circuit receives first and second input voltages, and outputs a first sampling signal according to the first and second input voltages. The first sampling signal represents a differential voltage which indicates a difference between the first input voltage and the second input voltage. The assist sampling circuit receives the first and second input voltages, and outputs a second sampling signal according to the first and second input voltages. The second sampling signal represents the differential voltage. The processing circuit is coupled to the main sampling circuit and the assist sampling circuit, and selects a larger one of currents or voltages of the first and second sampling signals as a sampling result to be outputted.