A moisture-wicking article of headwear includes a first layer of material formed from a polyester yarn, a second layer of material formed from a polyester yarn, and an absorbent layer positioned between the first layer of material and the second layer of material at a front of the article of headwear. The article of headwear is configured to temporarily store perspiration produced by a wearer's forehead area and transport the perspiration to the sides and back of the article of headwear where it can subsequently evaporate or be harmlessly released.