An organic electroluminescence device includes a first electrode, a hole transport region on the first electrode, an emission layer on the hole transport region, an electron transport region on the emission layer, and a second electrode on the electron transport region, wherein the emission layer includes a polycyclic compound containing one electron donor and one electron acceptor, and the electron donor includes an azaborine group and the electron acceptor includes any one of a cyano group, a carbonyl group, a boron group, a sulfonyl group, a sulfinyl group, a phosphine oxide group, a nitrogen-containing five-membered ring, or a nitrogen-containing six-membered monocyclic ring.