Invention Grant
- Patent Title: Atomically dispersed platinum-group metal-free catalysts and method for synthesis of the same
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Application No.: US17531461Application Date: 2021-11-19
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Publication No.: US11978912B2Publication Date: 2024-05-07
- Inventor: Gang Wu , Hui Xu , Shengwen Liu , Shuo Ding
- Applicant: The Research Foundation for The State University of New York , Giner, Inc.
- Applicant Address: US NY Buffalo
- Assignee: The Research Foundation for the State University of New York,Giner, Inc.
- Current Assignee: The Research Foundation for the State University of New York,Giner, Inc.
- Current Assignee Address: US NY Amherst; US MA Newton
- Agency: KRIEGSMAN & KRIEGSMAN
- Main IPC: H01M4/90
- IPC: H01M4/90 ; H01M8/10

Abstract:
Atomically dispersed platinum-group metal-free catalyst and method for synthesizing the same. According to one embodiment, the catalyst is made by a method in which, in a first step, a metal oxide/zeolitic imidazolate frameworks (ZIF) composite is formed by combining (i) nanoparticles of an oxide of at least one of iron, cobalt, nickel, manganese, and copper, (ii) a hydrated zinc salt, and (iii) an imidazole. Then, in a second step, the metal oxide/ZIF composite is thermally activated, i.e., carbonized, to form an M-N—C catalyst. Thereafter, the M-N—C catalyst may be mixed with a quantity of ammonium chloride, and then the M-N—C/NH4Cl mixture may be pyrolyzed. The foregoing NH4Cl treatment may improve the intrinsic activity of the catalyst. Then, a thin layer of nitrogen-doped carbon may be added to NH4Cl-treated M-N—C catalyst by chemical vapor deposition (CVD). Such CVD treatment may improve the stability of the catalyst.
Public/Granted literature
- US20220190356A1 ATOMICALLY DISPERSED PLATINUM-GROUP METAL-FREE CATALYSTS AND METHOD FOR SYNTHESIS OF THE SAME Public/Granted day:2022-06-16
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