Invention Grant
- Patent Title: Method for regenerating a catalyst which is spent and regenerated by a hydrodesulfurization process of gasolines
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Application No.: US17414725Application Date: 2019-12-10
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Publication No.: US11992826B2Publication Date: 2024-05-28
- Inventor: Elodie Devers , Etienne Girard , Philibert Leflaive
- Applicant: IFP Energies nouvelles
- Applicant Address: FR Rueil-Malmaison
- Assignee: IFP ENERGIES NOUVELLES
- Current Assignee: IFP ENERGIES NOUVELLES
- Current Assignee Address: FR Rueil-Malmaison
- Agency: Millen, White, Zelano & Branigan, P.C.
- Agent Csaba Henter
- Priority: FR 73239 2018.12.18
- International Application: PCT/EP2019/084437 2019.12.10
- International Announcement: WO2020/126676A 2020.06.25
- Date entered country: 2021-06-16
- Main IPC: B01J23/882
- IPC: B01J23/882 ; B01J23/94 ; B01J27/16 ; B01J35/10 ; B01J35/61 ; B01J37/02 ; B01J38/02 ; B01J38/12 ; B01J38/52 ; C10G45/04

Abstract:
A process for rejuvenating an at least partially spent catalyst resulting from a hydrodesulfurization process of a sulfur-containing olefinic gasoline cut, where the at least partially spent catalyst result is from a fresh catalyst a metal from group VIII, a metal from group VIb, and an oxide support, where the process includes
a) regenerating the at least partially spent catalyst in an oxygen-containing gas stream at a temperature between 350° C. and 550° C.,
b) the regenerated catalyst is brought into contact with an impregnation solution containing a compound containing a metal from group VIb, the molar ratio of the metal from group VIb added per metal from group VIb already present in the regenerated catalyst being between 0.15 and 2.5 mol/mol,
c) a drying stage is carried out at a temperature of less than 200° C., and
the use of the rejuvenated catalyst in a hydrodesulfurization process.
a) regenerating the at least partially spent catalyst in an oxygen-containing gas stream at a temperature between 350° C. and 550° C.,
b) the regenerated catalyst is brought into contact with an impregnation solution containing a compound containing a metal from group VIb, the molar ratio of the metal from group VIb added per metal from group VIb already present in the regenerated catalyst being between 0.15 and 2.5 mol/mol,
c) a drying stage is carried out at a temperature of less than 200° C., and
the use of the rejuvenated catalyst in a hydrodesulfurization process.
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