An ultrasonic testing system of dual robot arms and an ultrasonic testing method for use in testing quality of surface and interior of a workpiece. The system includes an extension rod provided between a tail-end of a master robot arm and an emitting probe and/or between a tail-end of a slave robot arm and a receiving probe. One or more connected extension rod rotating shafts is provided between the extension rod and the emitting probe or between the extension rod and the receiving probe. The method uses an X-axis constraint method to convert posture data of the discrete points in a trajectory file of the tested workpiece into Euler angles, and constrain the X-axes of the auxiliary coordinate systems at the same time so that the positive direction of the X-axis of each of the auxiliary coordinate systems is the trajectory tangent direction.