This steel sheet has a predetermined chemical composition, in which the area ratio of plate martensite is 10% or more, the average grain size of prior austenite grains is 2.0 μm to 10.0 μm, the maximum diameter thereof is 20.0 μm or less, the amount of solid solution C in martensite is 0.20 mass % or less, the average carbide size is 0.25 μm or less, the crystal orientation difference between plate martensite and another martensite adjacent thereto in the same prior austenite grain is 10.0° or less, and the P concentration at grain boundaries of the prior austenite grains is 4.0 at % or less.