The application relates to a light guide film, a production method thereof and a light guide device. An upper surface of the light guide film is a light exit surface and a lower surface is a light incident surface; the lower surface of the light guide film is smooth and is used for being connected with the substrate; a plurality of hollow ultrastructures are disposed in the light guide film, the hollow ultrastructure close to the lower surface of the light guide film is a conduction reflecting surface, and a gap between every two adjacent ultrastructures is a light exit gap.