An organic compound has a structure as shown in Formula (I). The compound has a phosphorus-oxygen five-membered ring combined with a five-membered ring as an electron acceptor unit. The compound has a high luminous efficiency and a lower material cost than phosphorescent metal complexes. The compound can be built into a stack structure of organic optoelectronic device, such as OLED. The resultant organic optoelectronic device includes an anode, a cathode, and at least one organic thin film located between the anode and the cathode, the organic thin film contains the compound as shown in Formula (I).