An electronic device may comprise a plurality of antennas, at least one processor, and an RF circuit. The at least one processor may be configured to identify at least one channel measurement configuration associated with a second RAT different from a first RAT in a state in which the electronic device is connected to a first communication network based on the first RAT, perform measurement on at least one measurement object identified based on at least some of the at least one channel measurement configuration, using at least one first antenna among the plurality of antennas, detect an event requiring a switch of an antenna for performing the measurement, and control the RF circuit to perform the measurement, using at least one second antenna different from the at least one first antenna among the plurality of antennas, based on detection of the event.