Invention Application
US20110137054A1 PROCESS FOR THE MANUFACTURE OF A 1,2-EPOXIDE 有权
1,2-环氧化物的制备方法

  • Patent Title: PROCESS FOR THE MANUFACTURE OF A 1,2-EPOXIDE
  • Patent Title (中): 1,2-环氧化物的制备方法
  • Application No.: US13056793
    Application Date: 2009-07-09
  • Publication No.: US20110137054A1
    Publication Date: 2011-06-09
  • Inventor: Ron PostmaPrasad Muppa
  • Applicant: Ron PostmaPrasad Muppa
  • Priority: EP08075680.2 20080801
  • International Application: PCT/EP2009/004977 WO 20090709
  • Main IPC: C07D301/12
  • IPC: C07D301/12 C07D301/06
PROCESS FOR THE MANUFACTURE OF A 1,2-EPOXIDE
Abstract:
The invention relates to a process for the manufacture of a 1,2-epoxide by catalytic oxidation of a terminal olefin with hydrogen peroxide wherein the catalytic oxidation is performed in a biphasic system comprising an organic phase and an aqueous reaction medium, wherein a water-soluble manganese complex is used as oxidation catalyst, wherein a terminal olefin is used with a solubility at 20° C. of at least 0.01 to 100 g in 1 liter water, and wherein the molar ratio of terminal olefin to hydrogen peroxide is in the range of from 1:0.1 to 1:2.
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