An optical communication transmitting device includes a substrate, a first layer with a first optical refractive index formed on the substrate, a waveguide unit formed with a second optical refractive index formed on the first layer, and a second layer with a third optical refractive index covered on the top of the waveguide unit. The second optical refractive index is greater than the first optical refractive index. The second optical refractive index is greater than the third optical refractive index. The waveguide unit is formed from a photo-resistor layer by a high energy light source exposure.