A method and an apparatus for detecting hidden hazardous substance including the steps of: performing terahertz imaging for a detected object; judging whether there is a suspicious area containing the hidden hazardous substance in a terahertz image of the detected object obtained by the terahertz imaging; performing a multi-wavelength spectroscopy measurement to the suspicious area, determining whether the hazardous substance is contained in the suspicious area according to results of multi-wavelength spectroscopy measurement; and outputting the image of the detected object and hazardous substance detecting result. Also disclosed is an apparatus for implementing the method for detecting the hidden hazardous substance according to the present invention. Determination of the hidden hazardous substance can be performed from the perspectives of shape features and substance composition, thus the accuracy of detection is greatly increased.