Invention Application
- Patent Title: PROCESS FOR THE PREPARATION OF HETEROPHASIC PROPYLENE POLYMER COMPOSITIONS
- Patent Title (中): 制备异构丙烯聚合物组合物的方法
-
Application No.: US14358753Application Date: 2012-11-07
-
Publication No.: US20140316069A1Publication Date: 2014-10-23
- Inventor: Monica Galvan , Roberto Pantaleoni , Ofelia Fusco , Benedetta Gaddi , Andreas Neumann , Antonio Mazzucco , Gianni Collina , Marco Ciarafoni
- Applicant: Basell Poliolefine Italia S.r.l.
- Applicant Address: IT Milano
- Assignee: Basell Polilefine Italia S.r.l.
- Current Assignee: Basell Polilefine Italia S.r.l.
- Current Assignee Address: IT Milano
- Priority: EP11189458.0 20111117
- International Application: PCT/EP2012/071974 WO 20121107
- Main IPC: C08L23/12
- IPC: C08L23/12

Abstract:
A process for the preparation of propylene polymer compositions comprising from 50 to 90% by weight of a propylene (co)polymer fraction insoluble in xylene at 25° C., and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25° C., said process comprising: (i) a first step of polymerizing propylene in the optional presence of ethylene and/or C4-C10 alpha olefins, to produce a propylene (co)polymer being for at least 85% by weight insoluble in xylene at 25° C.; and (ii) a successive step, carried out in gas-phase, in the presence of the product coming from step (i), of copolymerizing a mixture of ethylene with one or more α-olefins CH2═CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer; the process being carried out in the presence of a catalyst system comprising: the product obtained by contacting: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two internal electron donor compounds one of which being present in an amount from 35 to 90% by mol with respect to the total amount of donors and being selected from succinates and the other being selected from 1,3-diethers, the total amount of internal electron donor compounds being lower than 14.0% by weight with respect to the total weight of the solid catalyst component; with (b) an aluminum hydrocarbyl compound, and optionally with (c) an external electron donor compound.
Public/Granted literature
- US09752023B2 Process for the preparation of heterophasic propylene polymer compositions Public/Granted day:2017-09-05
Information query