Invention Application
US20160129426A1 CATALYST FOR THE OXYCHLORINATION OF ETHYLENE TO 1, 2-DICHLOROETHANE 有权
乙烯氧化成1,2-二氯乙烷的催化剂

CATALYST FOR THE OXYCHLORINATION OF ETHYLENE TO 1, 2-DICHLOROETHANE
Abstract:
This invention relates to a catalyst containing from about 2 up to about 8% by wt. of copper, zero up to about 0.6 moles/kg of one or more alkali metal(s), from about 0.08 up about 0.85 moles/kg of one or more alkaline earth metals and from about 0.09 up to about 0.9 moles/kg of one or more transition metals selected from the group consisting of Mn, Re and mixtures thereof, where all the metals are impregnated in form of their chlorides or other water soluble salts on a fluidizable support with a BET surface area of from about 80 up to about 220 m2/g. A process for the oxychlorination of ethylene to form 1,2-dichloroethane using such a catalyst having good activity, good selectivity and low tendency to stickiness in fluidized bed oxychlorination reactions.
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