A vapor sensor comprises a sensor element (110), a cooling member (140), and an operating circuit (160). The sensor element comprises: a first conductive electrode; a second conductive electrode; and a dielectric microporous material at least partially disposed between and contacting the first and second conductive electrodes. The cooling member is in contact with, and configured to cool, the sensor element. The operating circuit is in electrical communication with the first and second conductive electrodes, and is capable of creating a voltage difference between the first and second conductive electrodes such that the sensor element has a capacitance-related property, and monitoring a capacitance-related property of the sensor element. A method of using the vapor sensor to detect an analyte vapor is also disclosed.