Provided is a phosphor that emits red light, is represented by the general formula, A2MF6:Mn, and exhibits little reduction in intensity even when exposed to a high-temperature, high-humidity atmosphere over a long period of time. Also provided is a light-emitting device using said phosphor. The present invention is a phosphor in which the main crystal phase thereof is represented by the general formula, A2MF6:Mn. The element A is an alkali metal element including at least K, and the element M is one or more tetravalent elements selected from the group consisting of Si, Ge, Sn, Ti, Zr, and Hf. The phosphor has a coating layer on the surface thereof. The coating layer is a hydrophobic organic substance having a hydrophobicity of 10% or more.