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US06482945B2 Process for producing epsilon-caprolactam and apparatus for the process 失效
用于生产ε-己内酰胺的方法和该方法的装置

Process for producing epsilon-caprolactam and apparatus for the process
Abstract:
A process is provided for producing &egr;-caprolactam from cyclohexanone oxime. The process comprises a evaporation step of a mixture of cyclohexanone oxime and a solvent by introducing the mixture into a fluidized bed in which inert particles is fluidized by an inert gas, the particles having heat enough to evaporate the mixture; and a rearrangement step of cyclohexanone oxime in the evaporated mixture into &egr;-caprolactam by a gas phase Beckmann rearrangement reaction using a solid catalyst, excluding a catalyst consisting of a boric acid or a boron oxide.
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