Invention Grant
- Patent Title: Process for the production of ethers, typically thf
- Patent Title (中): 用于生产醚的方法,通常为
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Application No.: US10483524Application Date: 2002-07-10
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Publication No.: US06936727B2Publication Date: 2005-08-30
- Inventor: David Mark Sutton , Andrew George Hiles , Graham Reed , John Anthony Stannard
- Applicant: David Mark Sutton , Andrew George Hiles , Graham Reed , John Anthony Stannard
- Applicant Address: GB London
- Assignee: Davy Process Technology Limited
- Current Assignee: Davy Process Technology Limited
- Current Assignee Address: GB London
- Agency: Davidson, Davidson & Kappel, LLC
- Priority: GB0117090 20010712
- International Application: PCT/GB02/03195 WO 20020710
- International Announcement: WO03/00644 WO 20030123
- Main IPC: C07B61/00
- IPC: C07B61/00 ; C07D307/08

Abstract:
A process is described for the production of ethers, typically terahydrofuran, by reaction of a corresponding organic feed material selected from dicarboxylic acids and/or anhydrides, monoesters of dicarboxylic acids and/or anhydrides, diesters of dicarboxylic acids and/or anhydrides, lactones, and mixtures of two or more thereof in the presence of hydrogen which comprises the steps of: (a) supplying a stream comprising the organic feed material to a first vaporisation zone and contacting said feed with cycle gas comprising hydrogen such that at least a portion of the feed material is vaporised by and into the cycle gas; (b) supplying at least a portion of the cycle gas and the vaporised feed material to a first reaction zone comprising catalyst and operating under reaction conditions to allow hydrogenation and dehydration to occur; (c) recovering from the first reaction zone an intermediate product stream comprising unreacted feed material, cycle gas, desired product(s), and any co-products and by-products; (d) supplying the intermediate product stream to a second vaporisation zone and contacting it with additional feed material such that the said additional feed material is vaporised by and into the intermediate product stream; (e) supplying the product of step (d) to a subsequent reaction zone comprising catalyst and operating under reaction conditions to allow hydrogenation and, if required, dehydration to occur; and (f) recovering from the subsequent reaction zone a product stream comprising the ether.
Public/Granted literature
- US20040199026A1 Process for the production of ethers, typically thf Public/Granted day:2004-10-07
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