A system, method, and software that rapidly heats a diesel oxidation catalyst unit to an effective operating temperature at engine startup is disclosed. Upon ignition of an engine an electronic control unit is operable to lower a fresh air flow target value to a reduced fresh air flow target value as well as lower a valve opening limit of an exhaust gas recirculation valve to a reduced valve opening limit. The electronic control unit monitors a temperature value of a flow of exhaust entering the diesel oxidation catalyst unit until the temperature value reaches a first predetermined threshold value. After reaching the first predetermined threshold value, the electronic control unit causes the fuel system to set post-injection fueling to a predetermined post-injection fueling value until the temperature value of the flow of exhaust entering the diesel oxidation catalyst unit reaches a second predetermined threshold value.