Invention Grant
US07671234B2 Method for producing methylglycine-N,N-diethanoic acid-trialkali metal salts with a low by-product content
有权
具有低副产物含量的甲基甘氨酸-N,N-二乙酸 - 三烷基金属盐的制备方法
- Patent Title: Method for producing methylglycine-N,N-diethanoic acid-trialkali metal salts with a low by-product content
- Patent Title (中): 具有低副产物含量的甲基甘氨酸-N,N-二乙酸 - 三烷基金属盐的制备方法
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Application No.: US11913597Application Date: 2006-05-02
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Publication No.: US07671234B2Publication Date: 2010-03-02
- Inventor: Alfred Oftring , Gerold Braun , Friedrich Wirsing , Armin Stamm , Kai-Uwe Baldenius
- Applicant: Alfred Oftring , Gerold Braun , Friedrich Wirsing , Armin Stamm , Kai-Uwe Baldenius
- Applicant Address: DE Ludwigshafen
- Assignee: BASF Aktiengesellschaft
- Current Assignee: BASF Aktiengesellschaft
- Current Assignee Address: DE Ludwigshafen
- Agency: Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
- Priority: DE102005021055 20050506
- International Application: PCT/EP2006/061968 WO 20060502
- International Announcement: WO2006/120129 WO 20061116
- Main IPC: C07C227/26
- IPC: C07C227/26 ; C07C229/16

Abstract:
The invention relates to a process for preparing low-by-product, light-color methylglycine-N,N-diacetic acid tri(alkali metal) salt by alkaline hydrolysis of methylglycinediacetonitrile (MGDN), comprising the steps in the sequence (a) to (f): (a) mixing of MGDN with aqueous alkali at a temperature of ≦30° C.; (b) allowing the aqueous alkaline MGDN suspension to react at a temperature in the range from 10 to 30° C. over a period of from 0.1 to 10 h to form a solution; (c) allowing the solution from step (b) to react at a temperature in the range from 30 to 40° C. over a period of from 0.1 to 10 h; (d) optionally allowing the solution from step (c) to react at a temperature in the range from 50 to 80° C. over a period of from 0.5 to 2 h; (e) optionally allowing the solution from step (c) or (d) to react at a temperature in the range from 110 to 200° C. over a period of from 5 to 60 min; (f) hydrolysis and removal of ammonia of the solution obtained in step (c), (d) or (e) by stripping at a temperature of from 90 to 105° C.
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