A pixel structure suitable for disposing between a first scan line and a second scan line of a multi-domain vertical alignment liquid crystal display (MVA LCD) panel is provided. The pixel structure includes a first active device, a second active device, a first pixel electrode, a second pixel electrode and alignment members. The first active device is electrically connected with the first scan line and a data line of the LCD panel, and the second active device is also electrically connected therewith. The first and the second pixel electrode are electrically connected to the first and the second active device, respectively, and the first pixel electrode covers a part of the second scan line to form a compensation capacitance. Therefore, there is a voltage difference between the second pixel electrode and the first pixel electrode. The alignment members are disposed on the first and the second pixel electrode.