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US07683118B2 Process for preparing fluoropolymer dispersions 失效
氟聚合物分散体的制备方法

Process for preparing fluoropolymer dispersions
Abstract:
A process for preparing a fluoropolymer dispersion that is substantially anionic fluorinated surfactant free includes adding to a fluoropolymer dispersion a nonionic surfactant having a cloud point (CP) between 40 and 80° C. in a concentration of 1.5% to 50% by weight of the fluoropolymer, heating the dispersion up to a temperature Tc in a range of CP±10°C., decanting the dispersion in a reactor at Tc until obtaining a lower aqueous phase containing a concentrated fluoropolymer dispersion and an upper aqueous phase substantially not containing the fluoropolymer dispersion, washing the decanted dispersion with a solution of water and nonionic surfactant having a concentration of the nonionic surfactant of 0.5% to 50% by weight of the fluoropolymer, removing the upper aqueous phase from the upper part of the reactor, and discharge and recovery of the fluoropolymer dispersion.
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