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US07687426B2 Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process 失效
催化剂组成与单羧酸酯内给体和丙烯聚合过程

Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process
Abstract:
A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more monoesters of aromatic carboxylic acid internal electron donors; one or more aluminum containing cocatalyst; and a mixture of two or more different selectivity control agents, said SCA mixture comprising from 70 to 98 mol percent of one or more esters of one or more aromatic monocarboxylic acids or substituted derivatives thereof, and from 30 to 2 mol percent of one or more alkoxysilane compounds containing one or more 5- or 6-membered cyclic groups optionally containing one or more Group 14, 15 or 16 heteroatoms.
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