A transmissive diffraction grating includes a substrate and a plurality of ridges provided in a mutually parallel manner at constant periodicity p on the substrate. The ridges include a first layer, a second layer (refractive index n2: 2.0-2.5), and a third layer with non-continuous refractive indices, arranged in that order from the substrate outward. The first layer adjacent the substrate, in terms of its refractive index, exhibits a difference of 0.1 or less relative to the substrate. The second layer has a higher refractive index than the first layer and third layer and satisfies the following conditions. For a single ridge, the cross-sectional area S of a cross-section of the second layer perpendicular to the longitudinal direction of said ridge is in the range of 0.75p2k1θ2/(n2−1)