The invention discloses differing embodiments of thermal control coatings, spacecraft components having coatings, and methods for controlling the temperature of a component. In one embodiment, a thermal control coating under the invention may include one or more thermochromic multi-layer coatings and one or more solar rejection multi-layer coatings. The thermal control coating may have one or more transition temperatures at which the solar absorptance of the solar rejection coating substantially stays the same, while a thermal emittance of the thermochromic coating substantially changes.