Invention Grant
- Patent Title: Method of restoring catalytic activity to a spent hydroprocessing catalyst, a spent hydroprocessing catalyst having restored catalytic activity, and a hydroprocessing process
- Patent Title (中): 还原催化活性的方法,废还原加氢处理催化剂,已回收催化活性的废加氢催化剂和加氢处理方法
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Application No.: US11039677Application Date: 2005-01-19
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Publication No.: US07696120B2Publication Date: 2010-04-13
- Inventor: Josiane Marie-Rose Ginestra , James Dallas Seamans , Kenneth Scott Lee
- Applicant: Josiane Marie-Rose Ginestra , James Dallas Seamans , Kenneth Scott Lee
- Applicant Address: US TX Houston
- Assignee: Shell Oil Company
- Current Assignee: Shell Oil Company
- Current Assignee Address: US TX Houston
- Agent Charles W. Stewart
- Main IPC: B01J38/02
- IPC: B01J38/02 ; B01J21/20 ; B01J38/48 ; B01J38/62 ; B01J38/50 ; B01J38/12

Abstract:
Disclosed is method for restoring catalytic activity to a hydroprocessing catalyst that has become spent due to its use or to the deposition of carbon thereon. The method includes a carbon reduction step whereby carbon is removed from the spent hydroprocessing catalyst in a controlled manner to within a specifically defined concentration range. Following the carbon removal step, the resulting catalyst, having a reduced concentration of carbon, is subjected to a chelation treatment whereby the resulting carbon-reduced catalyst is contacted with a chelating agent and aged for a time period necessary for realizing the benefit from the controlled carbon reduction step. In a preferred embodiment, the catalyst resulting from the chelation treatment is subjected to a sulfurization treatment involving the incorporation of elemental sulfur therein and contacting therewith an olefin.
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