A safety switch of a gas stove includes a main member including a cone valve chamber, a first chamber, a second chamber, an input tunnel, a first output tunnel and a second output tunnel connected to the second chamber and outside. A close member, an electromagnetic valve and a first temperature controller are mounted in the valve chamber, the first chamber and the second chamber respectively. A second temperature controller and a knob set are mounted on the main member. The knob set is connected to the close member, the first temperature controller and the electromagnetic valve to turn the close member and activate the first temperature controller and the electromagnetic valve for control of gas flowing into the input tunnel or flowing out of the first and second output tunnels. The present invention provides the functions of sequent ignition, shut the gas when flame is out, and temperature control.