Invention Grant
- Patent Title: Process for the production of trimellitic acid
- Patent Title (中): 偏苯三酸生产工艺
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Application No.: US11919830Application Date: 2006-05-06
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Publication No.: US07709681B2Publication Date: 2010-05-04
- Inventor: Gian Luca Castiglioni , Roberto Pirola , Carlo Fumagalli
- Applicant: Gian Luca Castiglioni , Roberto Pirola , Carlo Fumagalli
- Applicant Address: IT Scanzorosciate
- Assignee: Polynt S.p.A.
- Current Assignee: Polynt S.p.A.
- Current Assignee Address: IT Scanzorosciate
- Agency: Polsinelli Shughart PC
- Agent Lisa V. Mueller
- Priority: EP05425324 20050513
- International Application: PCT/EP2006/004271 WO 20060506
- International Announcement: WO2006/119939 WO 20061116
- Main IPC: C07C51/255
- IPC: C07C51/255

Abstract:
Trimellitic acid is produced by oxidation of pseudocumene in acetic acid at temperatures between 130 and 240° C. in the presence of a catalyst composition containing cobalt, manganese and bromine. The process comprises the stages of: (i) simultaneously feeding pseudocumene and air or an oxygen-containing gas into a solution containing acetic acid and the catalyst composition, at an addition rate resulting in an oxygen concentration in the off-gas of less than 8 vol %, and at a temperature and a pressure sufficient to result in 5 to 25 mol % of the total amount of oxygen required to oxidize the pseudocumene to trimellitic acid being consumed, and (ii) feeding air or an oxygen-containing gas into the reaction mixture obtained in stage (i) until essentially all of the pseudocumene has been consumed and a molar yield of trimellitic acid of at least 90% has been obtained. There is no supplementation of catalyst after stage (i).
Public/Granted literature
- US20090043124A1 Process for the production of trimellitic acid Public/Granted day:2009-02-12
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