Invention Grant
- Patent Title: Method for preparing solid catalysts for ethylene polymerization and copolymerization
- Patent Title (中): 乙烯聚合和共聚固体催化剂的制备方法
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Application No.: US11577273Application Date: 2005-10-14
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Publication No.: US07718565B2Publication Date: 2010-05-18
- Inventor: Kap-Ku Kang , Byung-Ju Park , Jae-Kwon Jang , Young-Tae Jeong
- Applicant: Kap-Ku Kang , Byung-Ju Park , Jae-Kwon Jang , Young-Tae Jeong
- Applicant Address: KR Ulsan-si
- Assignee: Korea Petrochemical Ind. Co., Ltd.
- Current Assignee: Korea Petrochemical Ind. Co., Ltd.
- Current Assignee Address: KR Ulsan-si
- Agency: Rothwell, Figg, Ernst & Manbeck, P.C.
- Priority: KR10-2004-0082334 20041014
- International Application: PCT/KR2005/003431 WO 20051014
- International Announcement: WO2006/041264 WO 20060420
- Main IPC: C08F4/64
- IPC: C08F4/64 ; C08F4/642 ; C08F4/643 ; C08F4/649

Abstract:
The present invention relates to a method for preparing a solid catalyst for ethylene polymerization and/or copolymerization. More specifically, the present invention relates to a solid titanium catalyst supported in a magnesium support which has an extremely high catalytic activity, advantageous catalyst shape and a simple preparation process, capable of producing a polymer with a high bulk density, a narrow and uniform particle size distribution and a broad molecular weight distribution, and a method for preparation of the same. A silicon-containing magnesium compound is prepared by reacting an electron donor such as a silicon compound containing an alkoxy group of Formula 1, a silicon compound containing an alkoxy group of Formula 2, or a mixture thereof in a magnesium compound solution, and reacted with a titanium compound to obtain the solid catalyst of the present invention. Si(R1)(R2)(OR3)2 [Formula 1] wherein R1 is trimethylsilylmethyl or 2-phenylpropyl; R2 is linear, cyclic or branched alkyl of C3-C6 such as 1-hexyl, cyclohexyl, cyclopentyl, n-butyl, iso-butyl or propyl; and R3 is alkyl of C1-C3. R1aR2bSi(OR3)4−(a+b) [Formula 2] wherein R1 and R2 are individually hydrocarbon of C1-C12; R3 is hydrocarbon of C1-C5; and a=0 or 1, b=0 or 1.
Public/Granted literature
- US20070259777A1 Method for Preparing Solid Catalysts for Ethylene Polymerization and Copolymerization Public/Granted day:2007-11-08
Information query
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