Invention Grant
US07728174B2 Continuous hydrogenation processes for the preparation of xylylenediamines 失效
连续氢化方法制备苯二甲胺

  • Patent Title: Continuous hydrogenation processes for the preparation of xylylenediamines
  • Patent Title (中): 连续氢化方法制备苯二甲胺
  • Application No.: US11997759
    Application Date: 2006-07-27
  • Publication No.: US07728174B2
    Publication Date: 2010-06-01
  • Inventor: Randolf HugoKirsten DahmenSabine Huber
  • Applicant: Randolf HugoKirsten DahmenSabine Huber
  • Applicant Address: DE Ludwigshafen
  • Assignee: BASF SE
  • Current Assignee: BASF SE
  • Current Assignee Address: DE Ludwigshafen
  • Agency: Connolly Bove Lodge & Hutz LLP
  • Priority: DE102005036222 20050802; DE102005058417 20051207
  • International Application: PCT/EP2006/064731 WO 20060727
  • International Announcement: WO2007/014901 WO 20070208
  • Main IPC: C07C209/48
  • IPC: C07C209/48
Continuous hydrogenation processes for the preparation of xylylenediamines
Abstract:
Processes for preparing a xylylenediamine by continuous hydrogenation, wherein the processes comprise: introducing a liquid circulation stream comprising a phthalonitrile and ammonia into a reactor to continuously hydrogenate the phthalonitrile in the presence of a heterogenous catalyst and the ammonia such that a reactor effluent comprising the xylylenediamine is formed; drawing off a portion of the reactor effluent to provide a first recycle stream; mixing at least a portion of the first recycle stream in a mixing unit with liquid ammonia and fresh phthalonitrile in solid or molten form to provide a second recycle stream; and recycling the second recycle stream to the liquid circulation stream, or wherein the second recycle stream and any remaining unmixed portion of the first recycle stream are both recycled to the liquid circulation stream.
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