Invention Grant
US07732631B2 Eco-friendly process for the preparation of 2-Chlorobenzylidene-Malononitrile (CS)
有权
用于制备2-氯亚苄基 - 丙二腈(CS)的环保方法
- Patent Title: Eco-friendly process for the preparation of 2-Chlorobenzylidene-Malononitrile (CS)
- Patent Title (中): 用于制备2-氯亚苄基 - 丙二腈(CS)的环保方法
-
Application No.: US11587748Application Date: 2005-04-07
-
Publication No.: US07732631B2Publication Date: 2010-06-08
- Inventor: Ambuja Pande , Ramesh Chandra Malhotra , Kumaran Ganesan , Krishnamurthy Sekhar , Vinita Dubey
- Applicant: Ambuja Pande , Ramesh Chandra Malhotra , Kumaran Ganesan , Krishnamurthy Sekhar , Vinita Dubey
- Applicant Address: IN New Delhi
- Assignee: Director General, Defence Research & Development Organisation
- Current Assignee: Director General, Defence Research & Development Organisation
- Current Assignee Address: IN New Delhi
- Agency: The Webb Law Firm
- Priority: IN840/DEL/2004 20040507
- International Application: PCT/IN2005/000105 WO 20050407
- International Announcement: WO2005/108350 WO 20051117
- Main IPC: C07C255/00
- IPC: C07C255/00

Abstract:
An improved process for the preparation of 2-chlorobenzylidenemalononitrile (CS) comprising of the steps of: preparing malononitrile suspension by adding 5-20% (wt %) preferably 12-14% malononitrile to water while constantly stirring and then adding 0.05-0.5% (v/v) preferably 0.1-0% of a catalyst like piperidine, pyridine, 2-picoline, 3-picoline, 4-picoline or morpholine preferably piperidine piperidine with constant stirring at 20-30° C.; condensing the malononitrile suspension prepared in step (a) with 2-chlorobenzaldehyde by adding 10-15% (w/v) preferably 25-30%, of 2-chlorobenzaldehyde cover a period at 30-45 minutes so that the temperature of the reaction mixture remains below 50° C., constantly stirring for 20-40 minutes, then filtering the CS and drying it at 20-30° C. under water vacuum for 3-5 hrs.
Public/Granted literature
- US20080139837A1 Eco-Friendly Process for the Preparation of 2-Chlorobenzylidene-Malononitrile (Cs) Public/Granted day:2008-06-12
Information query