A multicore optical fibre includes a microstructured cladding material formed from a plurality of cladding elements arranged in an array and each cladding element comprising at least two different materials each having different refractive indices, and a plurality of core elements formed within interstitial regions between adjacent cladding elements. A fibre so formed may have a large number of cores per unit cross-sectional area as compared with prior art fibres, and thus allows the fibre to have relatively short distances between adjacent cores for a given required inter-core isolation. A fibre so formed has utility in many areas requiring high core density, such as inter-chip optical communication, or optical communication between circuit boards.