Invention Grant
- Patent Title: Continuous preparation of ethylene homopolymers or copolymers
- Patent Title (中): 连续制备乙烯均聚物或共聚物
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Application No.: US10577695Application Date: 2004-10-27
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Publication No.: US07737229B2Publication Date: 2010-06-15
- Inventor: Andrei Gonioukh , Gernot Köhler , Theo Teuber , Thomas Dröge
- Applicant: Andrei Gonioukh , Gernot Köhler , Theo Teuber , Thomas Dröge
- Applicant Address: DE Wesseling
- Assignee: Basell Polyolefine GmbH
- Current Assignee: Basell Polyolefine GmbH
- Current Assignee Address: DE Wesseling
- Agent Shao-Hua Guo
- Priority: DE10351262 20031031
- International Application: PCT/EP2004/012108 WO 20041027
- International Announcement: WO2005/049664 WO 20050602
- Main IPC: C08F2/00
- IPC: C08F2/00 ; C08F10/14

Abstract:
The invention relates to a process for the continuous preparation of ethylene homopolymers or copolymers in the presence of free-radical polymerization initiators and, if desired, molecular weight regulators at from 120° C. to 350° C. and pressures in the range from 100 to 4000 bar, in which the polymer is separated from unpolymerized ethylene in a high-pressure stage at a pressure of from 100 to 500 bar and at least one low-pressure stage at a pressure of from 1 to 100 bar and the ethylene separated off in the high-pressure stage is separated from remaining monomeric, oligomeric and/or polymeric constituents and recirculated to the inlet of the tube reactor in a high-pressure circuit and the ethylene separated off in the low-pressure stage is separated from remaining monomeric, oligomeric and/or polymeric constituents and recirculated to the inlet of the tube reactor in a low-pressure circuit. The initiator is used as a solution in an isoparaffinic solvent having a boiling point of not more than 160° C. and the solvent is separated from the other monomeric, oligomeric and/or polymeric constituents in the low-pressure circuit. The solvent is then, if appropriate after being admixed with fresh solvent, reused for dissolving initiator.
Public/Granted literature
- US20070123678A1 Continuous preparation of ethylene homopolymers or copolymers Public/Granted day:2007-05-31
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