Invention Grant
US07750077B2 Method for the production of polymethylvinylsiloxane resins with recycling of volatile oligoorganosiloxanes 有权
生产具有挥发性低聚有机硅氧烷再循环的聚甲基乙烯基硅氧烷树脂的方法

Method for the production of polymethylvinylsiloxane resins with recycling of volatile oligoorganosiloxanes
Abstract:
The invention relates to the field of silicon resins, particularly polymethylvinylsiloxane resins. The invention more specifically relates to a method for the production of polymethylvinylsiloxane resins comprising at least two different types of siloxy motifs R3SiO1/2 (motif M) and SiO4/2 (motif Q, optionally QOH), said method comprising the following steps: a) producing a siloxane resin comprising motifs Q by acidic hydrolysis of a siloxane resin precursor, preferably an alkaline silicate; b) functionalizing the siloxane resin obtained in step a) with halogenosilanes in the presence of an apolar solvent, the functionalizing generating sub-products including volatile oligosiloxanes (silox); c) recovering silox produced in step b) in a solution in the apolar solvent; and d) subjecting the resin functionalized in step b) to rearrangement with the aid of a strong base in order to eliminate the silanols, wherein at least a part of the silox produced during step b) and recovered in step c) is recycled.
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