Invention Grant
US07750077B2 Method for the production of polymethylvinylsiloxane resins with recycling of volatile oligoorganosiloxanes
有权
生产具有挥发性低聚有机硅氧烷再循环的聚甲基乙烯基硅氧烷树脂的方法
- Patent Title: Method for the production of polymethylvinylsiloxane resins with recycling of volatile oligoorganosiloxanes
- Patent Title (中): 生产具有挥发性低聚有机硅氧烷再循环的聚甲基乙烯基硅氧烷树脂的方法
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Application No.: US10544528Application Date: 2004-01-26
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Publication No.: US07750077B2Publication Date: 2010-07-06
- Inventor: Lucile Gambut-Garel , José-Louis Roca-Ortega , Didier Dahler , Gérard Mignani , Christian Allandrieu
- Applicant: Lucile Gambut-Garel , José-Louis Roca-Ortega , Didier Dahler , Gérard Mignani , Christian Allandrieu
- Applicant Address: FR Lyons
- Assignee: Bluestar Silicones France
- Current Assignee: Bluestar Silicones France
- Current Assignee Address: FR Lyons
- Agency: Buchanan Ingersoll & Rooney PC
- Priority: FR0301342 20030205
- International Application: PCT/FR2004/050028 WO 20040126
- International Announcement: WO2004/072149 WO 20040826
- Main IPC: C08G77/06
- IPC: C08G77/06

Abstract:
The invention relates to the field of silicon resins, particularly polymethylvinylsiloxane resins. The invention more specifically relates to a method for the production of polymethylvinylsiloxane resins comprising at least two different types of siloxy motifs R3SiO1/2 (motif M) and SiO4/2 (motif Q, optionally QOH), said method comprising the following steps: a) producing a siloxane resin comprising motifs Q by acidic hydrolysis of a siloxane resin precursor, preferably an alkaline silicate; b) functionalizing the siloxane resin obtained in step a) with halogenosilanes in the presence of an apolar solvent, the functionalizing generating sub-products including volatile oligosiloxanes (silox); c) recovering silox produced in step b) in a solution in the apolar solvent; and d) subjecting the resin functionalized in step b) to rearrangement with the aid of a strong base in order to eliminate the silanols, wherein at least a part of the silox produced during step b) and recovered in step c) is recycled.
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