Invention Grant
- Patent Title: Process for production of aromatic compounds
- Patent Title (中): 芳香族化合物生产工艺
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Application No.: US10588552Application Date: 2005-02-10
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Publication No.: US07781599B2Publication Date: 2010-08-24
- Inventor: Masaharu Nakamura , Eiichi Nakamura , Keiko Matsuo , Shingo Ito
- Applicant: Masaharu Nakamura , Eiichi Nakamura , Keiko Matsuo , Shingo Ito
- Applicant Address: JP Saitama
- Assignee: Japan Science and Technology Agency
- Current Assignee: Japan Science and Technology Agency
- Current Assignee Address: JP Saitama
- Agency: Foley & Lardner LLP
- Priority: JP2004-033941 20040210; JP2004-282578 20040928
- International Application: PCT/JP2005/002529 WO 20050210
- International Announcement: WO2005/075384 WO 20050818
- Main IPC: C07C2/02
- IPC: C07C2/02 ; C07C5/00 ; C07C69/76 ; C07D209/04

Abstract:
A problem of the present invention is to provide an economical process with minimized toxicity for producing an aromatic compound having a variety of substituents such as various alkyl groups, and the problem is solved by a process for production of an aromatic compound represented by formula (1) below, which comprises reacting a compound represented by formula (2) below with an aromatic magnesium reagent represented by formula (3a) below in the presence of an iron catalyst and a diamine compound: wherein R is an optionally substituted hydrocarbon group or a C3-C10 saturated or unsaturated ring group; A is an optionally substituted C4-C20 aromatic group or an optionally substituted heteroaromatic group; X is a halogen atom or a sulfonic acid ester; and Y1 is bromine, iodine, chlorine or a carbanion ligand.
Public/Granted literature
- US20070123734A1 Process for production of aromatic compounds Public/Granted day:2007-05-31
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