Invention Grant
US07781621B2 Hydroformylation method involving a cobalt-based catalyst in a non-aqueous ionic liquid
有权
在非水离子液体中涉及钴基催化剂的羰基化方法
- Patent Title: Hydroformylation method involving a cobalt-based catalyst in a non-aqueous ionic liquid
- Patent Title (中): 在非水离子液体中涉及钴基催化剂的羰基化方法
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Application No.: US12373409Application Date: 2007-06-22
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Publication No.: US07781621B2Publication Date: 2010-08-24
- Inventor: Helene Olivier-Bourbigou , Lucien Saussine , Lionel Magna , David Proriol
- Applicant: Helene Olivier-Bourbigou , Lucien Saussine , Lionel Magna , David Proriol
- Applicant Address: FR Rueil Malmaison Cedex
- Assignee: Institut Francais du Petrole
- Current Assignee: Institut Francais du Petrole
- Current Assignee Address: FR Rueil Malmaison Cedex
- Agency: Millen, White, Zelano & Branigan, P.C.
- Priority: FR0606497 20060713
- International Application: PCT/FR2007/001052 WO 20070622
- International Announcement: WO2008/006951 WO 20080117
- Main IPC: C07C45/50
- IPC: C07C45/50

Abstract:
In a method for hydroformylating olefinically unsaturated compounds by means of a cobalt-based catalyst, used in a non-aqueous ionic liquid, liquid at a temperature below 100° C. and comprising at least one cation Q+ and at least one anion A−, said method comprising at least a stage of reaction under pressure and at least a stage of separation of the phases by decantation, recycling of the catalyst is improved: through the use of a ligand selected from among the Lewis bases, more particularly pyridine derivatives, and simultaneously through the addition of this ligand in a post-reaction stage. At the end of this process, the organic phase containing the reaction products can be recovered and the ionic liquid phase containing the catalyst can be recycled to the hydroformylation reactor.
Public/Granted literature
- US20100010270A1 HYDROFORMYLATION METHOD INVOLVING A COBALT-BASED CATATLYST IN A NON-AQUEOUS IONIC LIQUID Public/Granted day:2010-01-14
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