A method of poling a ferroelectric sample suitable for use in a fuel injector of an internal combustion engine, the method comprising providing a ferroelectric sample having a stack of ferroelectric layers, wherein adjacent layers are separated by internal electrodes, forming a first group and a second group of electrodes; applying a multiaxial pressure to the ferroelectric sample; and generating an electric field between the first and second group of electrodes to pole the ferroelectric sample. The multiaxial pressure is ideally applied by means of a fluid, and the fluid may be an dielectric fluid or fuel.