Disclosed herein are an adhesive sheet and a manufacturing method thereof. The adhesive sheet comprises a polyvinyl chloride sheet formed of a polyvinyl chloride sheet comprising polyvinyl chloride, tourmaline and/or kiyoseki, and a flame retardant. The adhesive sheet may further comprise an antibacterial/deodorant layer formed on one side of the polyvinyl chloride sheet. The adhesive sheet has excellent ability to remove volatile organic compounds (VOCs), and excellent flame retardancy and printability.