A photosensitive electrochromic device includes a transparent non-conductive substrate, a thin-film solar cell module and an electrochromic solution. The thin-film solar cell module is a monolithic series-connected module and includes a transparent substrate and a plurality of thin-film solar cells located on the transparent substrate, wherein all the thin-film solar cells in the thin-film solar cell module are connected in series, and the above-mentioned electrochromic solution is located between the transparent non-conductive substrate and the thin-film solar cell module.