Invention Grant
US07863209B2 Methods for recycling catalyst compositions for aromatic ring halogenation
失效
用于再循环用于芳环卤化的催化剂组合物的方法
- Patent Title: Methods for recycling catalyst compositions for aromatic ring halogenation
- Patent Title (中): 用于再循环用于芳环卤化的催化剂组合物的方法
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Application No.: US10870352Application Date: 2004-06-16
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Publication No.: US07863209B2Publication Date: 2011-01-04
- Inventor: Balakrishnan Ganesan , Pradeep Jeevaji Nadkarni , Robert Edgar Colborn , Dan Hancu
- Applicant: Balakrishnan Ganesan , Pradeep Jeevaji Nadkarni , Robert Edgar Colborn , Dan Hancu
- Applicant Address: NL
- Assignee: Sabic Innovative Plastics IP B.V.
- Current Assignee: Sabic Innovative Plastics IP B.V.
- Current Assignee Address: NL
- Agency: Cantor Colburn LLP
- Main IPC: B01J38/42
- IPC: B01J38/42 ; B01J38/50 ; B01J31/00 ; C07C25/00 ; C01G3/04 ; C01G5/00 ; C01G7/00 ; C22B3/00 ; C22B11/06 ; C01G49/10

Abstract:
A method for recovering and reusing a ring-halogenation catalyst comprises: (A) contacting an aromatic compound with chlorine or bromine in the presence of a catalyst composition, where the catalyst composition comprises at least one salt comprising a Group 4-13 metal, a lanthanide metal, or an actinide metal; and at least one organic counterion derived from an organic acid having a pKa relative to water of 0 or greater; and at least one organic sulfur compound; to form a first product mixture comprising a monochloro or a monobromo aromatic compound and a Group 4-13 metal halide, a lanthanide metal halide or an actinide metal halide; (B) separating the metal halide from the first product mixture; and (C) contacting at least a portion of the metal halide and an aromatic compound with chlorine or bromine, and at least one organic sulfur compound; to form a second product mixture comprising a monochloro or a monobromo aromatic compound and a Group 4-13 metal halide, a lanthanide metal halide or an actinide metal halide.ving a pKa relative to water of 0 or greater; and at least one organic sulfur compound.
Public/Granted literature
- US20050283034A1 Methods for recycling catalyst compositions for aromatic ring halogenation Public/Granted day:2005-12-22
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