Invention Grant
US07863487B2 Hydroformylation process with improved control over product isomers
有权
加氢甲酰化方法改善了对产物异构体的控制
- Patent Title: Hydroformylation process with improved control over product isomers
- Patent Title (中): 加氢甲酰化方法改善了对产物异构体的控制
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Application No.: US12530889Application Date: 2008-03-12
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Publication No.: US07863487B2Publication Date: 2011-01-04
- Inventor: Thomas C. Eisenschmid , Glenn A. Miller , Ronald R. Peterson , Anthony G. Abatjoglon
- Applicant: Thomas C. Eisenschmid , Glenn A. Miller , Ronald R. Peterson , Anthony G. Abatjoglon
- Assignee: Dow Technology Investments LLC
- Current Assignee: Dow Technology Investments LLC
- Agent Marie F. Zukerman; Paul D. Hayhurst
- International Application: PCT/US2008/056602 WO 20080312
- International Announcement: WO2008/115740 WO 20080925
- Main IPC: C07C45/50
- IPC: C07C45/50

Abstract:
A continuous hydroformylation process for producing a mixture of aldehydes with improved flexibility and stability of a normal/branched (N/I) isomer ratio of the product aldehydes. The process involves reacting one or more olefinically-unsaturated compounds with carbon monoxide and hydrogen in the presence of an organopolyphosphite ligand and an organomonophosphite ligand, at least one of such ligands being bonded to a transition metal to form a transition metal-ligand complex hydroformylation catalyst; the process being conducted at a sub-stoichiometric molar ratio of organopolyphosphite ligand to transition metal, at a super-stoichiometric (>2/1) molar ratio of organomonophosphite ligand to transition metal, and at a carbon monoxide partial pressure in the inverse order region of the hydroformylation rate curve; and controlling and varying the isomer ratio by varying the concentration of organopolyphosphite ligand relative to transition metal.
Public/Granted literature
- US20100069680A1 HYDROFORMYLATION PROCESS WITH IMPROVED CONTROL OVER PRODUCT ISOMERS Public/Granted day:2010-03-18
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