A wireless Ad Hoc network including: a first terminal adapted to scan wireless resources in the network, to set quality information of each wireless resource in accordance with a state of each wireless resource, and to transmit a frame transmission request message containing quality identification information of each wireless resource in accordance with the quality information; and a second terminal adapted to select a wireless resource having a highest quality in accordance with the quality identification information of each wireless resource received from the first terminal and the quality information of each scanned wireless resource, and to transmit a frame transmission response message containing information on the selected wireless resource to the first terminal.