A center pin and a lithium ion secondary battery are provided. The center pin has a hollow body and a solid extinguishant is disposed inside the hollow body. The solid extinguishant has a certain shape that can fit into the hollow body, and can be made by compressing a powder extinguishing substance. Top and bottom of the center pin are initially closed by blocking members to reduce a dead volume in a battery. The top and bottom of the center pin open at high temperature so that the solid extinguishant is liquefied and flows out of the center pin. The liquefied extinguishant at the high temperature prevent the battery from igniting.