Invention Grant
US07888444B2 Production of isotactic and regiorandom polypropylene based polymer and block copolymers 有权
生产全同立构聚合物和聚丙烯基聚合物和嵌段共聚物

Production of isotactic and regiorandom polypropylene based polymer and block copolymers
Abstract:
One step ortho-alkylation of anilines with styrenes to give chiral anilines is obtained using a strong acid catalyst, e.g. CF3SO3H. Condensation of the product to give ligand and metallation gives complex which catalyzes polymerization of propylene to give isotactic propylene or regiorandom propylene of low PDI or blocks thereof, depending on polymerization temperature.
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