Invention Grant
US07897817B2 Resin-platinum complex and resin-supported platinum cluster catalyst
有权
树脂 - 铂络合物和树脂负载的铂簇催化剂
- Patent Title: Resin-platinum complex and resin-supported platinum cluster catalyst
- Patent Title (中): 树脂 - 铂络合物和树脂负载的铂簇催化剂
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Application No.: US11885734Application Date: 2005-12-01
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Publication No.: US07897817B2Publication Date: 2011-03-01
- Inventor: Yasuhiro Uozumi , Yoichi Yamada , Takayasu Arakawa
- Applicant: Yasuhiro Uozumi , Yoichi Yamada , Takayasu Arakawa
- Applicant Address: JP Tokyo
- Assignee: Inter-University Research Institute Corporation National Institutes of Natural Sciences
- Current Assignee: Inter-University Research Institute Corporation National Institutes of Natural Sciences
- Current Assignee Address: JP Tokyo
- Agency: Jenkins, Wilson, Taylor & Hunt, P.A.
- Priority: JP2005-064913 20050309
- International Application: PCT/JP2005/022068 WO 20051201
- International Announcement: WO2006/095477 WO 20060914
- Main IPC: C07C49/00
- IPC: C07C49/00

Abstract:
To provide a catalyst that has sufficient catalytic activity as a platinum catalyst and yet is readily separated from a target material and can be reused. A resin-supported platinum cluster catalyst containing a resin layer comprising a platinum particle core, the average diameter of which is from 1 nm to 10 nm, and a compound containing nitrogen (general formula R1NH2) surrounding the core. This catalyst can be obtained by forming a platinum complex from a compound containing nitrogen represented by the general formula R1NR22 (in the formula, R1 represents a carrier with a hydrophilic molecular chain and R2 represents a hydrogen atom, an alkyl group and the like) and a platinum compound represented by the general formula M(PtX4-nR3n)m (in the formula, M represents an alkali metal and the like, X represents a halogen atom and the like, R3 represents an unsaturated organic ligand, n represents an integer from zero to four and m represents an integer indicating the electrical charge of the metal, M) and allowing this platinum complex to react with a reducing agent in an aqueous solvent.
Public/Granted literature
- US20080176739A1 Resin-Platinum Complex and Resin-Supported Platinum Cluster Catalyst Public/Granted day:2008-07-24
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