A pixel structure suitable for being disposed on a substrate includes a thin film transistor (TFT), a first pixel electrode, a second pixel electrode, a scan line and a data line. The TFT disposed on the substrate includes a gate, a source, a first drain and a second drain. A main TFT is formed by the gate, the source and the first drain. A sub-thin film transistor (sub-TFT) is formed by the gate, the first drain and the second drain. The first pixel electrode is electrically connected to the first drain, and a portion of the first drain extends between the second pixel electrode and the substrate to form capacitor-coupling electrode. The second pixel electrode is electrically connected to the second drain of the sub-TFT. The scan line is disposed on the substrate and electrically connected to the gate, and the data line is electrically connected to the source.