Invention Grant
US07928184B2 Unstable terminal group decomposer, and stabilized polyacetal resin, manufacturing method, composition and molded article using the same
有权
不稳定的末端基团分解剂和稳定的聚缩醛树脂,制造方法,组合物和使用其的成型制品
- Patent Title: Unstable terminal group decomposer, and stabilized polyacetal resin, manufacturing method, composition and molded article using the same
- Patent Title (中): 不稳定的末端基团分解剂和稳定的聚缩醛树脂,制造方法,组合物和使用其的成型制品
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Application No.: US11886153Application Date: 2006-03-07
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Publication No.: US07928184B2Publication Date: 2011-04-19
- Inventor: Hatsuhiko Harashina , Hiroaki Nakao
- Applicant: Hatsuhiko Harashina , Hiroaki Nakao
- Applicant Address: JP Tokyo
- Assignee: Polyplastics Co., Ltd.
- Current Assignee: Polyplastics Co., Ltd.
- Current Assignee Address: JP Tokyo
- Agency: Nixon & Vanderhye P.C.
- Priority: JP2005-073629 20050315; JP2005-104235 20050331; JP2005-123658 20050421
- International Application: PCT/JP2006/304840 WO 20060307
- International Announcement: WO2006/098251 WO 20060921
- Main IPC: C08C1/14
- IPC: C08C1/14

Abstract:
The present invention provides a method of manufacturing a stabilized polyacetal resin, comprising the step of applying a heat treatment to a polyacetal resin having an unstable terminal group in the presence of an unstable terminal group decomposer selected from the following Group I, Group II and Group III, thereby decreasing the unstable terminal group: unstable terminal group decomposer of Group I: (I) a quaternary ammonium salt of an acidic cyclic amide compound, unstable terminal group decomposer of Group II: (II) a quaternary ammonium salt of a polycarboxylic acid intramolecularly having four or more carboxyl groups and/or a quaternary ammonium salt of an aminocarboxylic acid intramolecularly having one or more carboxyl group(s), unstable terminal group decomposer of Group III: (III) a quaternary ammonium salt, wherein a compound providing a counter-anion of a quaternary ammonium salt is at least one selected from the group consisting of the following (i) to (v): (i) a carbonic acid monoester and/or a metal bicarbonate, (ii) an acidic enol-based compound, (iii) a phenol-based and/or an alcohol-based compound, (iv) an acidic azole-based compound, and (v) at least one non-carboxylic acid-based compound selected from the group consisting of an organic sulfur compound, an organic phosphorus compound and an organic boron compound.
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