Invention Grant
US07928271B2 Process for producing 1,2,3,3,3-pentafluoropropene and related azeotropic compositions 有权
制备1,2,3,3,3-五氟丙烯和相关共沸组合物的方法

Process for producing 1,2,3,3,3-pentafluoropropene and related azeotropic compositions
Abstract:
A process for making CHF═CFCF3 is disclosed. The process involves (a) reacting CCl2FCF2CF3 with H2 in the presence of a catalytically effective amount of hydrogenation catalyst to form CH2FCF2CF3; and (b) dehydrofluorinating CH2FCF2CF3 from (a) to form CHF═CFCF3.Also disclosed are compositions including CCl3CF2CF3 and HF, wherein the HF is present in an effective amount to form an azeotropic combination with the CCl3CF2CF3; and compositions including CCl2FCF2CF3 and HF, wherein the HF is present in an effective amount to form an azeotropic combination with the CCl2FCF2CF3.
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