Invention Grant
- Patent Title: Method for producing water-soluble comb-shaped copolymers
- Patent Title (中): 生产水溶性梳状共聚物的方法
-
Application No.: US11921000Application Date: 2006-05-18
-
Publication No.: US07932339B2Publication Date: 2011-04-26
- Inventor: Olivier Braun , Paul Mallo , Jean-Louis Viovy , Jérémie Weber
- Applicant: Olivier Braun , Paul Mallo , Jean-Louis Viovy , Jérémie Weber
- Applicant Address: FR Paris FR Paris FR Paris
- Assignee: Centre National de la Recherche Scientifique,Institut Curie,Societe d'Exploitation de Produits pour les Industries Chimiques SEPPIC
- Current Assignee: Centre National de la Recherche Scientifique,Institut Curie,Societe d'Exploitation de Produits pour les Industries Chimiques SEPPIC
- Current Assignee Address: FR Paris FR Paris FR Paris
- Agency: Young & Thompson
- Priority: FR0551369 20050525
- International Application: PCT/FR2006/050452 WO 20060518
- International Announcement: WO2007/000535 WO 20070104
- Main IPC: C08F20/00
- IPC: C08F20/00

Abstract:
Method for producing a comb-shaped copolymer whose skeleton is of an acrylamide, acrylic acid, acryloyl aminoethanol or dimethyl acrylamide type and on which poly(N-alkyl acrylamide) or poly(N,N-5 dialkyl acrylamide lateral segments are grafted, includes (a) producing a telomer poly(N-alkyl acrylamide) or poly(N,N-dialkyl acrylamide) of formula (I) H2N—R1-Z-{CH2—C(R2) [C(═O)N(R3) (R4)]—}n—H (I) 10 by reacting in water a compound of formula (II) CH2═C(R2)—C(═O)—N(R3) (R4) (II) with a chain limiting compound of formula (III) Z-R1—NH2; (b) isolating the telomer of formula (I) obtained at a stage (a); (c) reacting in water the telomer of formula (I) obtained at stage (b) with an acid chloride of formula (IV) CH2═C(R5)—C(═O)—C1 at a molar ratio (IV)/(III) equal to or less than 10 and equal to or greater than 1 so that a macro monomer of formula (V) 20 CH2═C(R5)—C(═O)NH—R1-Z-{CH2—C(R2) [C(═O)N(R3) (R4)]—}n—H (V) is obtained; (d) isolating the macro monomer of formula (V) obtained at stage (c); (e) copolymerizing in water the macro monomer of formula (V) isolated at stage (d) with a monomer selected from acrylamide, acrylic acid, acryloyl-aminoethanol or dimethyl-acrylamide and, if necessary, (f) purifying the thus obtained copolymer.
Public/Granted literature
- US20100048839A1 Novel method for producing water-soluble comb-shaped copolymers Public/Granted day:2010-02-25
Information query